Means for rotating the polarization planh; of light and
for converting polarized light to non-polarized light

ABSTRACT

A LIGHT TRANSMISSIVE DEVICE WHICH WILL ROTATE THE PLANE OF POLARIZED LIGHT AND WILL ALSO DE-POLARIZE PLANE POLARIZED LIGHT PASSED THROUGH THE DEVICE, SAID DEVICE COMPRISING A PAIR OF DIRECTIONALLY ORIENTED SUPPORTING SURFACES SUCH AS UNIDIRECTIONALLY RUBBED GLASS OR PLASTIC PLATES, ROTATABLE RELATIVE TO EACH OTHER AND SEPRATED BY A THIN FILM OF A NON-OPTICALLY ACTIVE NEMATIC LIQUID CRYSTAL MATERIAL, THEDEVICE ACTING TO ROTATE THE PLANE OF THE POLARIZED LIGHT WHEN THE DIRECTIONALLY ORIENTED SURFACE FIRST CONTACTED BY THE ENTERING LIGHT IS EITHER PARALLEL OR PERPENDICULAR TO THE PLANE OF POLARIZATION OF THE ENTERING LIGHT AND THE REMAINING DIRECTIONALLY ORIENTED SURFACE IS ROTATED SO AS TO BRING ITS ORIENTED SURFACE TO THE DESIRED PLANE OF POLARIZATION FOR THE EXITING LIGHT, THE DEVICE ALSO ACTING TO CONVERT PLANE POLARIZED LIGHT TO NON-POLARIZED LIGHT WHEN THEORIENTED SURFACE FIRST CONTACTED BY THE ENTERING LIGHT LIES AT AN ANGLE OF 45* WITH RESPECT TO THE PLANE OF POLARIZATION OF THE ENTERING LIGHT AND THE DIRECTIONALLY ORIENTED SURFACES ARE PARALLEL TO EACH OTHER.

Feb. 5, 1974 J. F, Re. 27,911

MEANS FOR ROTATING THE POLARIZATION PLANE OF LIGHT AND FOR CONVERTINGPOLARIZED LIGHT TO NON-POLARIZED LIGHT Original Filed July 15, 1969INVENTOR John F. Dre yer BY yw, %& M 20 ATTORNEYS United States Patent27,911 MEANS FOR ROTATING THE POLARIZATION PLANE OF LIGHT AND FORCONVERTING POLARIZED LIGHT TO NON-POLARIZED LIGHT John F. Dreyer,Cincinnati, Ohio, assignor to Polacoat Incorporated, Cincinnati, OhioOriginal No. 3,592,526, dated July 13, 1971, Ser. No. 841,857, July 15,1969. Application for reissue Nov. 1, 1971, Ser. No. 194,610

Int. Cl. Gtl2b 5/30 US. Cl. 350l59 11 Claims Matter enclosed In heavybrackets [II appears in the original patent but forms no part of thisreissue specification; matter printed in italics indicates the additionsmade by reissue.

ABSTRACT OF THE DISCLOSURE A light transmissive device which will rotatethe plane of polarized light and will also de-polarize plane polarizedlight passed through the device, said device comprising a pair ofdirectionally oriented supporting surfaces, such as unidirectionallyrubbed glass or plastic plates, rotatable relative to each other andseparated by a thin film of a non-optically active nematic liquidcrystal material, the device acting to rotate the plane of the polarizedlight when the directionally oriented surface first contacted by theentering light is either parallel or perpendicular to the plane ofpolarization of the entering light and the remaining directionallyoriented surface is rotated so as to bring its oriented surface to thedesired plane of polarization for the exiting light, the device alsoacting to convert plane polarized light to non-polarized light when theoriented surface first contacted by the entering light lies at an angleof 45 with respect to the plane of polarization of the entering lightand the directionally oriented surfaces are parallel to each other.

BACKGROUND OF THE INVENTION While it has been proposed to rotate theplane of polarization of polarized light, it has heretofore beennecessary to utilize materials such as mica or stretched plastic torotate the plane of polarization to the desired degree. However, the useof either mica and stretched plastic induces eliptical or circularpolarization of the light, with accompanying color effects which, inmany instances, are undesirable in precision optical instruments. Thereare also applications wherein it is desirable to rotate the plane ofpolarization of relatively large areas of light; and the sizes of thedevices heretofore available have been limited by the size of the micaor cellulose acetate sheets which are available. In addition, it has notbeen possible to truly and uniformly de-polarize plane polarized lightwithout scattering or defusing the light which is passed through thede-polarizing system.

In contrast to the foregoing, the instant invention provides a simpleand effective means for rotating the plane of polarization of any sourceof light to any desired degree of rotation or to completely de-polarizethe light which is passed through the device, irrespective of theinitial plane of polarization of the light or on the degree to which itis polarized.

RESUME OF THE INVENTION The instant invention will find utility invarious optical instruments wherein it is desired to rotate the plane ofpolarization of the entering light or to de-polarize such light. It willalso find utility in literally any device which is sensitive to, oraffected by, polarized light, as for example a photometer.

The essence of the invention lies in the utilization of a thin film of anon-optically active nematic liquid crystal material between a pair ofsupporting surfaces which themselves are directionally oriented. Theoriented surfaces can be either transparent or translucent, preferablybeing in the form of essentially rigid glass or plastic plates. Theorientation of the surfaces which are in contact with the film ofnematic liquid crystal material is obtained by rubbing the surfaces, thedirection of rubbing determining the direction of orientation obtained.The rubbing may be readily done with a cloth using a slurry of rough inwater to assist in the rubbing operation. It is important that theoriented surfaces be clean and not contaminated by the presence of anycationic or other material which will be attracted to the orientedsurfaces so as to form an insulating film which will prevent theorientation effect on the liquid crystal material.

The thickness of the supporting plates does not constitute a limitationon the invention, nor does the particular material from which they areformed. Glass plates can be readily directionally oriented, as can mostplastics except for those which are cross-linked. However, where plasticplates are employed, care must be taken so that the plates will be inertwith respect to the nematic liquid crystal compound. Plastic materials,such as ethyl cellulose and methyl methacrylate resin, have been foundhighly suited for the purpose. Crystalline materials, with the exceptionof hard crystalline surfaces, such as sapphire, also have [has] a Beilbylayer which is permantly oriented by rubbing.

There are many known nematic liquid crystal materials which may beemployed. Preferably, the liquid crystal material should be essentiallycolorless and it should be inert to the plastic or other surfaces withwhich it is in contact. In addition, it should not be optically activewith reference to the levo or dextro rotary power of the material suchas is obtained by unsymmetrical groups on the molecules. Both lyotropicand thermotropic organic nematic materials may be used, as well aseutectic mixtures of the nematic compounds. Many of the organicthermotropic nematic compounds must be maintained at an elevatedtemperature, i.e., above room temperature, in order for them to exhibitthe nematic mesophase, but a number of recently discovered nematiccompounds are optically active at temperatures as low as 0 C. A veryuseful nematic material for room temperaturel's] work is that obtainedfrom the condensation of para normal butyl aniline andanisaldehydepAdditional examples of nematic compounds which areparticularly suited for the practice of the instant invention are foundin a co-pending application in the name of Elwood [Streble] Srrebel,Ser. No. 817,143, filed Apr. 17, 1969, and entitled Organic ThermotropicNematic Compounds. These compounds, which comprise para-substitutedalkyl or alkoxy benzylidenephenylamines having also para, or ortho andpara substituents of the phenylamine ring, are particularly suited forthe practice of the instant invention in hat they have low viscositiesand can be readily handled and formed into thin films. Exemplarly oflyotropic compounds are bromophenanthrene sulfonic acid, or amaranth inproper concentration with a solvent.

The thickness of the nematic liquid crystal film between the supportingsurfaces is not critical, although film thicknesses between .0005 and.015 inch are preferred. Below .005 inch color effects tend to appear,whereas as the film thickness increases, the film tends to become hazy,and films having a thickness in excess of .015 inch will lose theirclarity. A preferred film thickness is .001 inch. The liquid characterof the room temperature materials permits easy rotation of thesupporting plates without destroying their rubbed orientation; andconsequently the angle of rotation of the light can be adjustedaccurately to any desired degree.

The desired film thickness can be readily maintained by spacing apartthe supporting surfaces by means of a gasket or mask of the desired filmthickness. Another method for maintaining proper spacing, particularlywhere large surface areas are involved, is to incorporate a smallquantity of inert particles, such as silica beads or glass powder,having cross-sectional dimensions equal to that of the desired spacing.

DESCRIPTION OF THE DRAWINGS FIG. l is a schematic plan view with partsbroken away illustrating the principles of the invention as applied to adevice for rotating the plane of polarized light.

FIG. 2 is a vertical sectional view taken along the line 22 of FIG. 1.

FIG. 3 is a schematic plan view with parts broken away illustrating theprinciples of the invention as applied to a device for de-polarizing asource of polarized light.

FIG. 4 is a plan view of a simple form of device in accordance with theinvention.

FIG. 5 is a vertical sectional view taken along the line 5-5 of FIG. 4.

DESCRIPTION OF THE PREFERRED EMBODIMENTS Referring first to FIGS. 1 and2, a polarizing filter is indicated at l which is adapted to receivelight from a light source 2. Upon passage of the light through thepolarizing filter 1, the light will be completely polarized, its planeof polarization being indicated by the solid arrows 3, as seen inFIG. 1. A first supporting surface 4 overlies the polarizing filter, thesupporting surface comprising a glass or plastic plate the uppermostsurface of which has been unidirectionally oriented by rubbing, thedirection of orientation of the first supporting surface being indicatedby the dotted arrows 5. The film of nematic liquid crystal material isindicated at 6 and, in the embodiment illustrated, the liquid film isenclosed within a gasket or mask 7 the thickness of which determines thethickness of the liquid crystal film. Such mask may be convenientlyformed from a transparent material, such as cellulose acetate. A secondsupporting surface 8 overlies the liquid crystal film and itsundersurface is also unidirectionally oriented, again by rubbing, asindicated by the dotted arrows 9.

With the supporting surfaces oriented in the manner illustrated in FIG.1, the plane of polarization of the exiting light on the viewing side ofthe device will be in the direction of the solid arrows 10, the plane ofpolarization being parallel to the direction of orientation of thesecond supporting surface, as indicated by the dotted arrows 9. Thus,the angle between the directions of orientation of the two supportingsurfaces, i.e., the angle defined between the dotted arrows 5 and 9,determines the degree to which the plane of polarization of the light isrotated. In the embodiment illustrated, it is shown rotated through anangle of 90.

It will be understood, however, that the angle of rotation may lieanywhere between 0 and 360, depending upon the extent to which thesupporting surface 8 is rotated relative to the supporting surface 5.Thus, by rotating the second surface 8, the plane of polarization of theexiting light can be rotated at will to any desired angle relative tothe plane of polarization of the entering light. The degree of rotationis uniform for all visible Wave lengths and no color effects areobserved if a proper thickness of the nematic liquid crystal film ismaintained and the film is chosen so as to have no optical activity.

The same rotational effect can be achieved by rotating the firstsupporting surface 4 so that its direction of orientation, lies at rightangles with respect to the plane of polarization of the entering light.In other words, the orientation of the supporting surface on the side ofthe 4 device where the light enters may be either parallel orperpendicular to the plane of polarization of the entering light.Otherwise, as will be discussed hereinafter, some of the enteringpolarized light will be transformed into non-polarized light.

It also should be pointed out that the device may be used without thepolarizing filter 1. While such filter is preferred to unify the planeof polarization of the entering light, the device will be operativewithout the polarizing filter to whatever extent polarized light isemitted by the original light source. Consequently, the invention may beutilized with any source of light irrespective of its degree ofpolarization or its plane of polarization.

Where it is desired to de-polarize the light passing through the device,the parts will be oriented in the position illustrated in FIG. 3,wherein it will be seen that the first supporting surface 4 has beenrotated so that its direction of orientation, as exemplified by thedotted arrows 5, lies at an angle of 45 with respect to the plane ofpolarization of the entering light, as exemplified by the solid arrows3. In addition, the second supporting surface 8 has been rotated so thatits direction of orientation, as exemplified by the dotted arrows 9, isparallel to the direction of orientation of the first supportingsurface. Where this condition exists, the exiting light will benon-polarized, as indicated by the crossed arrows 11. In other words,when the oriented directions of both supporting surfaces are paralleland lie at an angle of 45 with respect to the plane of polarization ofthe entering light, the exiting light will be completely depolarized.Under these circumstances, the device becomes a means for convertingplane polarized light into non-polarized light without inducingelliptical or circular polarization of the light; and suchde-polarization takes place uniformly throughout the spectrum.

If the direction of orientation of either or both of the supportingsurfaces is rotated so as to lie at any angle less than, or greaterthan, 45 with respect to the plane of polarization of the entering light(other than 0 or a combination of the effects of rotating the plane ofpolarization and de-polarizing the light will take place. In otherwords, as the direction of orientation of the supporting surfaces movesaway from an angle of 45 with respect to the plane of polarization ofthe polarized light which passes through the device on the viewing sidewill be rotated, the degree of rotation depending upon the extent towhich the polar oriented surfaces are rotated.

In the embodiment illustrated in FIG. 3, it will be noted that thegasket or mask which establishes the desired thickness of the nematicliquid crystal material has been eliminated, the supporting surfacesbeing separated from each other by the desired film thickness by meansof inert particles 12, such as silica beads or glass powder, dispersedin the liquid crystal film.

FIGS. 4 and 5 illustrate an exemplary form of device in accordance withthe instant invention wherein the liquid crystal film 6 is retainedbetween the supporting surfaces 4 and 8 by means of an O-ring 13 whichmay be conveniently received in mating annular grooves 14 and 15 formedin the film contacting surfaces of the supporting plates. The assemblymay be conveniently mounted in a frame 16 having a cutaway portion 17which acts to expose marginal edge portions of the supporting plates,one such edge portion being indicated at 8a in FIG. 4. For ease ofrotation, the edges of the supporting plates may be milled, as indicatedat 18, or otherwise configured to permit ready engagement for rotationalmovement.

It should be evident that diverse types of frames and mounting means maybe employed, depending upon the size and intended mode of operation ofthe device. For example, assemblies may be made up with the direction oforientation of the two supporting surfaces in fixed relationship to eachother, their directions of orientation being parallel if the device isto be used to de-polarize the light;

or their directions of orientation may be at any desired angle where itis desired to rotate the plane of polarization by a fixed angle.

Similarly, by employing liquid crystal materials which are no longerfluid, fixed filters or cells can be made. For example, it has beenfound that isobutyl methacrylate resin can be added to a number ofliquid crystal materials, depending upon their chemical constitution, upto 50% by volume. The combination may be made by using a suitable mutualsolvent, such as toluol. After coating one of the oriented supportingsurfaces with the liquid crystalresin mixture, the solvent is evaporatedand the second oriented surface is placed in contact with the film soformed.

Various other modifications may be made in the invention withoutdeparting from its spirit and purpose. For example, by rubbing differentparts of the supporting surfaces in different direction, patterns can beproduced which will give corresponding variations in the rotation orde-poraization of the entering light, thereby producing interesting andvariable visual effects.

The embodiments of the invention in which an exclusive property orprivilege is claimed are defined as follows:

1. In combination in a device for altering the plane of polarization ofpolarized light, a first light transmissive supporting plate having adirectional oriented surface, a second light transmissive supportingplate also having a directionally oriented surface, and a thin film of anonoptically active nematic liquid crystal material juxtaposed betweenand in contact with the directionally oriented surfaces of saidsupporting plates, said supporting plates being rotatable relative toeach other.

2. The device claimed in claim 1 wherein said film of liquid crystalmaterial has a thickness of from 0.0005 to 0.015 inch.

3. The device claimed in claim 2 including a polarizing filter mountedto the outside of one of said supporting plates.

4. The device claimed in claim 3 wherein at least one of said supportingplates is rotatable relative to said polarizing filter.

5. The device claimed in claim 1 including means for spacing apart thesaid supporting plates by a distance equal to the desired thickness ofsaid film of nematic liquid crystal material.

6. The device claimed in claim 5 wherein said lastnamed means comprisesa gasket or mask interposed between the marginal edges of saidsupporting plates, the said liquid crystal material lying within theconfines of said gasket or mask.

7. The device claimed in claim 5 wherein said lastnamed means comprisesessentially uniform particles of an inert material dispersed in saidliquid crystal material.

8. A light transmissive device which will rotate the [plan] plane ofpolarized light and will also depolarize plane polarized light, saiddevice comprising a pair of unidirectionally oriented essentially planarsurfaces rotatable relative to each other, said surfaces being separatedby a thin film of a non-optically [nonoptically] active nematic liquidcrystal material in contact with the said surfaces, the device servingto rotate the plane of the polarized light when the unidirectionallyoriented surface first contacted by light entering the device is eitherparallel or perpendicular to the plane of polarization of the enteringlight and the remaining unidirectionally oriented surface is rotated soas to bring its oriented surface to the desired plane of polarizationfor the exiting light, the device serving to convert plane polarizedlight to nonpolarized light when the unidirectionally oriented surfacefirst contacted by the entering light lies at an angle of 45 withrespect to the plane of polarization of the entering light and bothunidirectionally oriented surfaces are parallel.

9. In combination in a device for altering the plane of polarization ofpolarized light, a first light transmissive supporting plate having adirectionally oriented surface, a second light transmissive supportingplate also having a directionally oriented surface, and a thin film of anematic non-optically active nematic liquid crystal material juxtaposedbetween and in contact with the directionally oriented surfaces of saidsupporting plates and means mounting said supporting plates inpermanently fixed position relative to each other.

10. The device claimed in claim 9 wherein the direetionally orientedsurfaces of said plates are in fixed parallel relationship to eachother.

11. The device claimed in claim 9 wherein the directionally orientedsurfaces lie at right angles to each other.

References Cited The following references, cited by the Examiner, are ofrecord in the patented file of this patent or the original patent.

UNITED STATES PATENTS 3,431,044 3/1969 Clark 350-159 X 3,499,702 3/1970Goldmacher et al. 350- FOREIGN PATENTS 441,274 1/1936 Great Britain350-150 OTHER REFERENCES Pinsky, Reflective Liquid Crystal Displays,"Electronics World, November 1968, pp. 29 and 58.

JOHN K. CORBIN, Primary Examiner M. I. TOKAR, Assistant Examiner US. Cl.X.R.

